Controlling thermally induced electron transfer in cyano-bridged molecular squares: from solid state to solution.
LI, Dongfeng
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
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Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
LI, Dongfeng
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
< Reduce
Centre de recherches Paul Pascal [CRPP]
Key Laboratory of Pesticide and Chemical Biology of Ministry of Education
Language
en
Article de revue
This item was published in
Chemistry - A European Journal. 2011, vol. 17, n° 42, p. 11704-11708
Wiley-VCH Verlag
English Abstract
A new cyano-based {Fe<sub>2</sub>Co<sub>2</sub>} complex has been synthesized, and its optical and magnetic properties described in the frame of an intramolecular electron transfer. Due to methyl functionalization of the ...Read more >
A new cyano-based {Fe<sub>2</sub>Co<sub>2</sub>} complex has been synthesized, and its optical and magnetic properties described in the frame of an intramolecular electron transfer. Due to methyl functionalization of the ligand, which gives good solubility to this complex, its thermally induced switchable behavior has been transferred to solution and finely tuned over a broad temperature range by adjusting the solvent composition and polarity.Read less <
Keywords
Cyanides
Electron transfer
Magnetic properties
Solvent effects
UV/Vis spectroscopy
Origin
Hal imported