The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2*nH2O (with n = 2) spin crossover compound proven by single crystal investigations
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GROSJEAN, Arnaud | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | DARO, Nathalie | |
| hal.structure.identifier | Institut Européen de Chimie et Biologie [IECB] | |
| dc.contributor.author | KAUFFMANN, Brice | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | KAIBA, Abdellah | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | GUIONNEAU, Philippe | |
| dc.date.issued | 2011 | |
| dc.identifier.issn | 1359-7345 | |
| dc.description.abstractEn | The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)<sub>3</sub>]X<sub>2</sub>*<i>n</i>H<sub>2</sub>O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO<sub>3</sub> and <i>n</i> = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz)<sub>3</sub>] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds. | |
| dc.language.iso | en | |
| dc.publisher | Royal Society of Chemistry | |
| dc.subject.en | Spin transition | |
| dc.subject.en | Chemical compounds | |
| dc.subject.en | Crystal structure | |
| dc.subject.en | Single crystal | |
| dc.title.en | The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2*nH2O (with n = 2) spin crossover compound proven by single crystal investigations | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1039/C1CC14220H | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Chemical Communications | |
| bordeaux.page | 12382-12384 | |
| bordeaux.volume | 47 | |
| bordeaux.issue | 45 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00641727 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00641727v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Chemical%20Communications&rft.date=2011&rft.volume=47&rft.issue=45&rft.spage=12382-12384&rft.epage=12382-12384&rft.eissn=1359-7345&rft.issn=1359-7345&rft.au=GROSJEAN,%20Arnaud&DARO,%20Nathalie&KAUFFMANN,%20Brice&KAIBA,%20Abdellah&L%C3%89TARD,%20Jean-Fran%C3%A7ois&rft.genre=article |
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