The 1-D polymeric structure of the [Fe(NH2trz)3](NO3)2*nH2O (with n = 2) spin crossover compound proven by single crystal investigations
Language
en
Article de revue
This item was published in
Chemical Communications. 2011, vol. 47, n° 45, p. 12382-12384
Royal Society of Chemistry
English Abstract
The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)<sub>3</sub>]X<sub>2</sub>*<i>n</i>H<sub>2</sub>O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, ...Read more >
The first single crystal-based description of a spin transition compound from the patented [Fe(Rtrz)<sub>3</sub>]X<sub>2</sub>*<i>n</i>H<sub>2</sub>O family is reported, properly the compound with Rtrz = 4-amino-1,2,4-triazole, X = NO<sub>3</sub> and <i>n</i> = 2. This study definitively proves the 1-D polymeric nature of the crystal structure and allows a description of the [Fe(Rtrz)<sub>3</sub>] chains, as well as of the anions and water implementation within the crystal lattice opening the possibility of subsequent investigations of the structure-property correlation within this peculiar family of spin transition compounds.Read less <
English Keywords
Spin transition
Chemical compounds
Crystal structure
Single crystal
Origin
Hal imported