Stabilization of highest-oxidation states of transition metals and the induced electronic phenomena in oxidic perovskite structures
Langue
en
Article de revue
Ce document a été publié dans
Journal of Inorganic and General Chemistry / Zeitschrift für anorganische und allgemeine Chemie. 2005, vol. 631, n° 2-3, p. 556-563
Wiley-VCH Verlag
Résumé en anglais
In oxides the stabilization of the highest oxidation states n+ of transition metals leads to the stabilization of strong covalent Mn+-O bonds. Such very covalent bonds can induce electronic phenomena as spin transitions ...Lire la suite >
Mots clés en anglais
High oxidation states
Transition metal cations
Electronic phenomena
Spin transition
Insulator metal transition