Synthesis, crystal structure, magnetic properties, and electronic structure of the new ternary vanadate CuMnVO4
Language
en
Article de revue
This item was published in
Inorganic Chemistry. 2005, vol. vol. 44, n° 9, p. p. 3087-3093
American Chemical Society
English Abstract
A new magnetic oxide, CuMnVO4, was prepared, and its crystal structure was determined by single-crystal X-ray diffraction. The magnetic properties of CuMnVO4 were characterized by magnetic susceptibility and specific heat ...Read more >
A new magnetic oxide, CuMnVO4, was prepared, and its crystal structure was determined by single-crystal X-ray diffraction. The magnetic properties of CuMnVO4 were characterized by magnetic susceptibility and specific heat measurements, and the spin exchange interactions of CuMnVO4 were analyzed on the basis of spin-polarized electronic band structure calculations. CuMnVO4 contains MnO4 chains made up of edge-sharing MnO6 octahedra containing high-spin Mn2+ cations. Our work shows that CuMnVO4 undergoes a three-dimensional antiferromagnetic transition at ~20 K. Both the intrachain and interchain spin exchanges are antiferromagnetic, and the interchain spin exchange is not negligible compared to the intrachain spin exchange.Read less <
English Keywords
Spin-exchange interactions
Lithium batteries
Diffraction
Density
LiMnVO4
Oxides
Origin
Hal imported