Structural characterization of a photoinduced molecular switch.
Language
en
Article de revue
This item was published in
Journal of the American Chemical Society. 2002, vol. 124, n° 2, p. 194-195
American Chemical Society
English Abstract
The crystal structures in both irradiated and nonirradiated states of a photoinduced molecular switch based on the spin-crossover phenomenon are presented. From the structural point of view, the light-induced metastable ...Read more >
The crystal structures in both irradiated and nonirradiated states of a photoinduced molecular switch based on the spin-crossover phenomenon are presented. From the structural point of view, the light-induced metastable high-spin state of the spin-crossover complex [Fe(phen)2(NCS)2] (phen = 1,10-phenanthroline) shows significant differences with the low-spin state but also with the thermally induced high-spin state.Read less <
English Keywords
Crystal structure
Molecular switch
Photoinduced effect
Origin
Hal imported