High oxygen pressures and the improvement of the Mn+ -- O chemical bond through the stabilization of the highest oxidation states (n+)
PRESNIAKOV, Igor A.
Lomonosov Moscow State University = Université d'État Lomonossov de Moscou [Moscou] [MSU]
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Lomonosov Moscow State University = Université d'État Lomonossov de Moscou [Moscou] [MSU]
PRESNIAKOV, Igor A.
Lomonosov Moscow State University = Université d'État Lomonossov de Moscou [Moscou] [MSU]
< Réduire
Lomonosov Moscow State University = Université d'État Lomonossov de Moscou [Moscou] [MSU]
Langue
en
Article de revue
Ce document a été publié dans
High Pressure Research. 2002, vol. 22, n° 3-4, p. 555-557
Taylor & Francis
Résumé en anglais
An evolution of local structure of Ni and chemical bonding, Ni(III)-O in perovskite lattice with strongly distorted structure is investigated with 57Fe Mössbauer spectroscopy. The Mössbauer spectra for 57Fe-doped TlNiO3 ...Lire la suite >
An evolution of local structure of Ni and chemical bonding, Ni(III)-O in perovskite lattice with strongly distorted structure is investigated with 57Fe Mössbauer spectroscopy. The Mössbauer spectra for 57Fe-doped TlNiO3 were resolved to two quadrupole doublets with different isomer shifts, which underlines a partial charge disproportionation phenomenon: 2Fe3+ -> Fe3+alpha +Fe3-alpha. This result supports the existence of two different crystallographic sites for Ni in the distorted perovskite lattice.< Réduire
Mots clés en anglais
Trivalent nickel
Perovskite
Mössbauer spectroscopy
Charge disproportionation
Origine
Importé de halUnités de recherche