Relaxor or classical ferroelectric behavior in ceramics with composition Sr2-xA1+xNb5O15-xFx (A = Na, K)
EL ALAOUI-BELGHITI, H.
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie du Solide Minéral
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Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie du Solide Minéral
EL ALAOUI-BELGHITI, H.
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie du Solide Minéral
< Leer menos
Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
Laboratoire de Chimie du Solide Minéral
Idioma
en
Article de revue
Este ítem está publicado en
Materials Letters. 2002, vol. 55, n° 3, p. 138-144
Elsevier
Resumen en inglés
By partial cationic and anionic substitutions in NaNbO3-SrNb2O6 and KNbO3-SrNb2O6 systems, two solid solutions have been obtained: Sr2−xNa1+xNb5O15−xFx and Sr2−xK1+xNb5O15−xFx. They crystallize in the tetragonal tungsten ...Leer más >
By partial cationic and anionic substitutions in NaNbO3-SrNb2O6 and KNbO3-SrNb2O6 systems, two solid solutions have been obtained: Sr2−xNa1+xNb5O15−xFx and Sr2−xK1+xNb5O15−xFx. They crystallize in the tetragonal tungsten bronze (TTB) type structure, which is related to that of the perovskite. The replacement of oxygen by fluorine causes a decrease of the Curie temperature. A weak F-O substitution rate increases the compactness, which leads to higher dielectric constant with good piezoelectric and pyroelectric characteristics. A relatively higher F-O substitution rate induces aferroelectricrelaxorbehavior. Such relaxorferroelectricceramics with lead-free compositions can be of great interest for environment-friendly applications.< Leer menos
Palabras clave en inglés
Disorder
Relaxor
TTB
Ceramics
Orígen
Importado de HalCentros de investigación