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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorPARADIS, Nicolas
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCHASTANET, Guillaume
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorLÉTARD, Jean-François
dc.date.issued2012
dc.identifier.issn1434-1948
dc.description.abstractEnWith the ultimate goal of rationally inducing overlap between the stable high spin state (HSSS) and the metastable high spin state (HSMS) generated by a rapid frozen effect, a series of [FexMn1-x(bpp)2](BF4)2 [bpp = 2,6-bis(pyrazol-3-yl)pyridine] complexes was prepared. For all the materials, the thermal spin crossover (SCO) properties were measured and the stability of the metastable HSMS state was probed through the determination of the T(TIESST) value associated with the Thermally-Induced Excited Spin-State Trapping effect. The overlap between the two systems was observed for x ≤ 0.90 and the consequences on the shape and the completeness of the SCO behavior were discussed.
dc.language.isoen
dc.publisherWiley-VCH Verlag
dc.title.enWhen stable and metastable HS states meet in spin-crossover compounds
dc.typeArticle de revue
dc.identifier.doi10.1002/ejic.201200297
dc.subject.halChimie/Matériaux
bordeaux.journalEuropean Journal of Inorganic Chemistry
bordeaux.page3618-3624
bordeaux.issue22
bordeaux.peerReviewedoui
hal.identifierhal-00720679
hal.version1
hal.popularnon
hal.audienceInternationale
dc.subject.itCoordination chemistry
dc.subject.itTransition metals
dc.subject.itIron
dc.subject.itSpin crossover
dc.subject.itMagnetic properties
dc.subject.itMetal dilution
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00720679v1
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