Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework.
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | SCIORTINO, Natasha F. | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | SCHERL-GRUENWALD, Katrin R. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | CHASTANET, Guillaume | |
| hal.structure.identifier | X-ray Science Division [XSD] | |
| dc.contributor.author | HALDER, Gregory J. | |
| hal.structure.identifier | X-ray Science Division [XSD] | |
| dc.contributor.author | CHAPMAN, Karena W. | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | LÉTARD, Jean-François | |
| hal.structure.identifier | School of Chemistry | |
| dc.contributor.author | KEPERT, Cameron J. | |
| dc.date.issued | 2012 | |
| dc.identifier.issn | 1433-7851 | |
| dc.description.abstractEn | Multistability is exhibited by a metal-organic framework material that undergoes unique three-step spin crossover with 20 K thermal hysteresis. The stepwise transition is coupled to a three-step structural transformation that defines four distinct structural states. The material also exhibits reversible photo-induced spin crossover. | |
| dc.language.iso | en | |
| dc.publisher | Wiley-VCH Verlag | |
| dc.subject.en | Hofmann framework | |
| dc.subject.en | Metal-organic frameworks | |
| dc.subject.en | Molecular electronics | |
| dc.subject.en | Photophysics | |
| dc.subject.en | Spin crossover | |
| dc.title.en | Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework. | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1002/anie.201204387 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Angewandte Chemie International Edition | |
| bordeaux.page | 10154-10158 | |
| bordeaux.volume | 51 | |
| bordeaux.issue | 40 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00738081 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00738081v1 | |
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