Hysteretic Three-Step Spin Crossover in a Thermo- and Photochromic 3D Pillared Hofmann-type Metal-Organic Framework.
Language
en
Article de revue
This item was published in
Angewandte Chemie International Edition. 2012, vol. 51, n° 40, p. 10154-10158
Wiley-VCH Verlag
English Abstract
Multistability is exhibited by a metal-organic framework material that undergoes unique three-step spin crossover with 20 K thermal hysteresis. The stepwise transition is coupled to a three-step structural transformation ...Read more >
Multistability is exhibited by a metal-organic framework material that undergoes unique three-step spin crossover with 20 K thermal hysteresis. The stepwise transition is coupled to a three-step structural transformation that defines four distinct structural states. The material also exhibits reversible photo-induced spin crossover.Read less <
English Keywords
Hofmann framework
Metal-organic frameworks
Molecular electronics
Photophysics
Spin crossover
Origin
Hal imported