A face-capped [Fe(4)L(4)](8+) spin crossover tetrahedral cage
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Chemical Communications. 2013, vol. 49, n° 16, p. 1597-1599
Royal Society of Chemistry
Resumen en inglés
Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe(4)L(4)](BF(4))(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements ...Leer más >
Reported here is a face-capped Fe(ii) molecular tetrahedron, [Fe(4)L(4)](BF(4))(8), . Single crystal X-ray diffraction at 153 and 293 K suggest spin crossover (SCO) and variable temperature magnetic susceptibility measurements confirm displays thermally driven SCO behaviour in the solid state and in dilute acetone solution centred around 284-288 K.< Leer menos
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