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hal.structure.identifierLaboratoire de Chimie du Solide Minéral
dc.contributor.authorEL HADRAMI, Abdelouahab
hal.structure.identifierLaboratoire de Chimie du Solide Minéral
dc.contributor.authorAOUAD, H.
hal.structure.identifierLaboratoire de Chimie du Solide Minéral
dc.contributor.authorMESNAOUI, Mohamed
hal.structure.identifierLaboratoire de Chimie du Solide Minéral
dc.contributor.authorMAAZAZ, A.
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorVIDEAU, Jean-Jacques
dc.date.issued2002
dc.identifier.issn0167-577X
dc.description.abstractEnPhosphate glasses of composition (100−y)[50 P2O5-15 ZnO-(35−x) PbO-x CdO]-yAl2O3 have been prepared and studied. In the alumina-free glasses (y=0), the effect of CdO substitution for PbO involves a strengthening of the glass network with a maximum of the aqueous durability for x values close to 20. For x=20, the addition of Al2O3 in the composition range 0≤y≤8 leads to a progressive increase of the phosphate network reticulation. For y>4, an unexpected change in the properties is observed, which probably results from a cationic rearrangement in the glass structure. For y=8, the chemical durability is equivalent to that of window glass. Such glasses are potential candidates for the storage of toxic heavy metals.
dc.language.isoen
dc.publisherElsevier
dc.subject.enPhosphate glasses
dc.subject.enPhysical properties
dc.subject.enWater durability
dc.subject.enHeavy toxic metals
dc.title.enStorage of toxic heavy metals in phosphate glasses: physical and water durability properties
dc.typeArticle de revue
dc.identifier.doi10.1016/S0167-577X(02)00891-1
dc.subject.halChimie/Matériaux
bordeaux.journalMaterials Letters
bordeaux.page894-898
bordeaux.volume57
bordeaux.issue4
bordeaux.peerReviewedoui
hal.identifierhal-00816900
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00816900v1
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