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Polynuclear coordination compounds as precursors for CuFe2O4

hal.structure.identifierCoordination Chemistry Laboratory
dc.contributor.authorMARINESCU, Gabriela
hal.structure.identifierCoordination Chemistry Laboratory
dc.contributor.authorPATRON, Luminita
hal.structure.identifierCoordination Chemistry Laboratory
dc.contributor.authorCARP, Oana
hal.structure.identifierInstitute of Atomic Physics
dc.contributor.authorDIAMANDESCU, Lucian
hal.structure.identifierCoordination Chemistry Laboratory
dc.contributor.authorSTANICA, Nicolae
hal.structure.identifierUniversity Politehnica of Bucarest
dc.contributor.authorMEGHEA, Aurelia
hal.structure.identifierDepartment of Inorganic Chemistry
dc.contributor.authorBREZEANU, Maria
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorGRENIER, Jean-Claude
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorETOURNEAU, Jean
dc.date.issued2002
dc.identifier.issn0959-9428
dc.description.abstractEnThe possibility of obtaining copper ferrite through the thermal decomposition of the two polynuclear coordination compounds: (NH4)8[Fe2Cu(C2O4)8] (I) and [Fe2Cu(C2O4)2(OH)4]*4H2O (II) was considered. The polynuclear compounds were characterized by various physical chemical techniques, e.g., IR, UV-VIS, EPR, Mössbauer spectra, thermal analysis and magnetic measurements. The final products obtained after thermal decomposition of the complex compounds were analysed by X-ray diffraction. A mixture of tetragonal CuFe2O4, α-Fe2O3 and CuO is generated from the thermolysis of compound I, while a clean tetragonal CuFe2O4 with saturation magnetization of 26.89 emu g−1 is obtained from compound II.
dc.language.isoen
dc.publisherRoyal Society of Chemistry
dc.subject.enCoordination compounds
dc.subject.enInorganic chemistry
dc.subject.enCopper
dc.subject.enPolynuclear
dc.title.enPolynuclear coordination compounds as precursors for CuFe2O4
dc.typeArticle de revue
dc.identifier.doi10.1039/B206604C
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Materials Chemistry
bordeaux.page3458-3462
bordeaux.volume12
bordeaux.issue12
bordeaux.peerReviewedoui
hal.identifierhal-00817697
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00817697v1
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