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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
hal.structure.identifierDepartment of Material Science
dc.contributor.authorMALAKHO, Artem
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorDUSSAUZE, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGIN, Evelyne
hal.structure.identifierDepartment of Chemistry
dc.contributor.authorLAZORYAK, Bogdan
hal.structure.identifierLaboratoire de Physico-Chimie Moléculaire [LPCM]
dc.contributor.authorRODRIGUEZ, Vincent
hal.structure.identifierLaboratoire de Physico-Chimie Moléculaire [LPCM]
dc.contributor.authorADAMIETZ, Frédéric
dc.date.issued2005
dc.identifier.issn0022-4596
dc.description.abstractEnCrystallization of glasses with compositions (1−x)(0.95 NaPO3+0.05 Na2B4O7)+xNb2O5, x=0.4, 0.43, 0.45, 0.48 was investigated by differential scanning calorimetry and X-ray powder diffraction. Crystallization of two phases was observed in the glasses with x=0.43–0.48. First phase is a sodium niobate with the structure of tetragonal tungsten bronze (Tc~720-760°C) and second phase is Na4Nb8P4O32 (Tc~830-850°C). The crystallization of sodium niobate is correlated with increasing of nonlinear optical efficiency reported for thermally poled glasses with x>0.4...
dc.language.isoen
dc.publisherElsevier
dc.subject.enSecond harmonic generation
dc.subject.enBorophosphates
dc.subject.enGlasses
dc.subject.enNiobium
dc.subject.enCrystallization
dc.subject.enPoled
dc.title.enCrystallization and second harmonic generation in thermally poled niobium borophosphate glasses
dc.typeArticle de revue
dc.identifier.doi10.1016/j.jssc.2005.03.035
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Solid State Chemistry
bordeaux.page1888-1897
bordeaux.volume178
bordeaux.issue6
bordeaux.peerReviewedoui
hal.identifierhal-00081857
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00081857v1
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