Structural, magnetic and electrical properties of the ternary silicide Gd6Co1.67Si3 derived from the hexagonal Ho4Co3.07 (or Ho6Co4.61) type structure
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en
Article de revue
Este ítem está publicado en
Zeitschrift fur Naturforschung B. 2006, vol. 61, n° 7, p. 825-832
Verlag der Zeitschrift Fuer Naturforschung
Resumen en inglés
The title compound was discovered as an impurity phase in many GdCoSi samples. It crystallizes in the hexagonal space group P63/m with a = 11.7787(5) and c = 4.1640(2) A° . Using X-ray powder diffraction, an ordered ...Leer más >
The title compound was discovered as an impurity phase in many GdCoSi samples. It crystallizes in the hexagonal space group P63/m with a = 11.7787(5) and c = 4.1640(2) A° . Using X-ray powder diffraction, an ordered distribution between Co and Si was found but one site is not fully occupied by Co for steric reasons. Magnetization measurements reveal that Gd6Co1.67Si3 exhibits a ferromagnetic transition at TC = 294(2) K, a Curie temperature similar to that reported for pure gadolinium. This magnetic ordering has been confirmed by electrical resistivity investigations.< Leer menos
Palabras clave en inglés
Intermetallics
Rare-earth
Electron microscopy
Crystal chemistry
Magnetic properties
Electrical resistance
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