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hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorMATHONIÈRE, Corine
hal.structure.identifierDepartment of Chemistry and Biochemistry
dc.contributor.authorLIN, Hsiu-Jung
dc.contributor.authorSIRETANU, Diana
hal.structure.identifierCentre de recherches Paul Pascal [CRPP]
dc.contributor.authorCLÉRAC, Rodolphe
hal.structure.identifierDepartment of Chemistry and Biochemistry
dc.contributor.authorSMITH, Jeremy M.
dc.date.issued2013
dc.identifier.issn0002-7863
dc.description.abstractEnThe four-coordinate Fe(II) complex, PhB(MesIm)3Fe-N═PPh3 (1) has been previously reported to undergo a thermal spin-crossover (SCO) between high-spin (HS, S = 2) and low-spin (LS, S = 0) states. This complex is photoactive below 20 K, undergoing a photoinduced LS to HS spin state change, as determined by optical reflectivity and photomagnetic measurements. With continuous white light irradiation, 1 displays slow relaxation of the magnetization, i.e. single-molecule magnet (SMM) properties, at temperatures below 5 K. This complex provides a structural template for the design of new photoinduced mononuclear SMMs based on the SCO phenomenon.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enMolecular magnet
dc.subject.enComplex compounds
dc.subject.enSpin crossover
dc.title.enPhotoinduced Single-Molecule Magnet Properties in a Four-Coordinate Iron(II) Spin Crossover Complex.
dc.typeArticle de revue
dc.identifier.doi10.1021/ja410643s
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of the American Chemical Society
bordeaux.page19083-19086
bordeaux.volume135
bordeaux.issue51
bordeaux.peerReviewedoui
hal.identifierhal-00923480
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00923480v1
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