New Insights into the Side-Face Structure, Growth Aspects, and Reactivity of Agn Nanoprisms
Langue
en
Article de revue
Ce document a été publié dans
Langmuir. 2014, vol. 30, p. pp. 1424−1434
American Chemical Society
Résumé en anglais
We report an improved synthesis of colloidal Agn nanoprisms using carboxyl compounds (citrate or succinate) and long chain macromolecules (polyvinylpyrrolidone (PVP)). The side-facet structure of the triangular nanostructure ...Lire la suite >
We report an improved synthesis of colloidal Agn nanoprisms using carboxyl compounds (citrate or succinate) and long chain macromolecules (polyvinylpyrrolidone (PVP)). The side-facet structure of the triangular nanostructure was determined in detail using electron tomography in scanning transmission mode (3D STEM) and HRTEM. It has been found that they are built up by {100} facets with a single parallel twin plane. The best conditions for producing uniform Ag nanoprisms with tunable sizes and high yields in the presence of carboxyl compounds additive system are described, and a growth mechanism is proposed. This approach provides also a route to synthesize Ag nanodisks and Au−Ag alloyed nanoprisms.< Réduire
Mots clés en espagnol
Nanostructures
Macromolecules
Colloids
Origine
Importé de halUnités de recherche