Synthesis and characterization of O3-Na3LiFeSbO6: A new honeycomb ordered layered oxide
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SCHMIDT, Whitney | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | BERTHELOT, Romain | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | ÉTIENNE, Laetitia | |
| hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
| dc.contributor.author | WATTIAUX, Alain | |
| hal.structure.identifier | Department of Chemistry | |
| dc.contributor.author | SUBRAMANIAN, Mass A. | |
| dc.date.issued | 2014 | |
| dc.identifier.issn | 0025-5408 | |
| dc.description.abstractEn | A new compound Na3LiFeSbO6 has been synthesized by conventional solid state methods and investigated using X-ray diffraction, DC magnetic susceptibility, 57Fe Mössbauer spectroscopy and optical measurements. This compound crystallizes in a monoclinic unit cell and is related to a family of honeycomb ordered layered oxide materials where Na+ fills octahedral interlayer sites between Li1/3Fe1/3Sb1/3O2 slabs of edge sharing octahedra. Each SbO6 octahedron is surrounded by LiO6 and FeO6 octahedra creating a honeycomb arrangement within the slabs. Powder X-ray diffraction indicates the presence of stacking faults. This compound exhibits Curie-Weiss behavior at high temperatures and the effective magnetic moment verifies the presence of high spin Fe3+. The 57Fe Mössbauer spectroscopy confirms Fe3+ in an octahedral position and indicates disorder in the arrangement of LiO6 and FeO6 octahedra in the Li1/3Fe1/3Sb1/3O2 slabs. | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.subject.en | Layered compounds | |
| dc.subject.en | Magnetic properties | |
| dc.subject.en | Optical properties | |
| dc.subject.en | Mössbauer spectroscopy | |
| dc.subject.en | X-ray diffraction | |
| dc.title.en | Synthesis and characterization of O3-Na3LiFeSbO6: A new honeycomb ordered layered oxide | |
| dc.type | Article de revue | |
| dc.identifier.doi | 10.1016/j.materresbull.2013.10.049 | |
| dc.subject.hal | Chimie/Matériaux | |
| bordeaux.journal | Materials Research Bulletin | |
| bordeaux.page | 292-296 | |
| bordeaux.volume | 50 | |
| bordeaux.peerReviewed | oui | |
| hal.identifier | hal-00956475 | |
| hal.version | 1 | |
| hal.popular | non | |
| hal.audience | Internationale | |
| hal.origin.link | https://hal.archives-ouvertes.fr//hal-00956475v1 | |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Materials%20Research%20Bulletin&rft.date=2014&rft.volume=50&rft.spage=292-296&rft.epage=292-296&rft.eissn=0025-5408&rft.issn=0025-5408&rft.au=SCHMIDT,%20Whitney&BERTHELOT,%20Romain&%C3%89TIENNE,%20Laetitia&WATTIAUX,%20Alain&SUBRAMANIAN,%20Mass%20A.&rft.genre=article |
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