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hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorCREMOUX, Tatiana
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorDUSSAUZE, Marc
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorFARGIN, Evelyne
hal.structure.identifierInstitut de Chimie de la Matière Condensée de Bordeaux [ICMCB]
dc.contributor.authorCARDINAL, Thierry
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorTALAGA, David
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorADAMIETZ, Frédéric
hal.structure.identifierInstitut des Sciences Moléculaires [ISM]
dc.contributor.authorRODRIGUEZ, Vincent
dc.date.issued2014
dc.identifier.issn1932-7447
dc.description.abstractEnMolecular and ionic species of nitrogen oxides have been injected, formed, and then trapped within a borosilicate glass during a thermal poling process. This original observation denotes a new aspect of poling mechanisms for ionic glasses. For each poled borosilicate glasses studied, compositional, structural, and second harmonic generation profiles of their subanodic polarized layers have been characterized. A description of the space charge implementation process, involving interactions between charged and chemically active species formed both within plasma discharges at the glass/electrode interface and within the polarized glass matrix, is proposed.
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.subject.enGlasses
dc.subject.enThermal poling process
dc.subject.enNitrogen oxides
dc.subject.enBorosilicate
dc.title.enTrapped molecular and ionic species in poled borosilicate glasses : toward a rationalized description of thermal poling in glasses
dc.typeArticle de revue
dc.identifier.doi10.1021/jp4101015
dc.subject.halChimie/Matériaux
bordeaux.journalJournal of Physical Chemistry C
bordeaux.page3716-3723
bordeaux.volume118
bordeaux.issue7
bordeaux.peerReviewedoui
hal.identifierhal-00968916
hal.version1
hal.popularnon
hal.audienceInternationale
hal.origin.linkhttps://hal.archives-ouvertes.fr//hal-00968916v1
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