Trapped molecular and ionic species in poled borosilicate glasses : toward a rationalized description of thermal poling in glasses
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | CREMOUX, Tatiana | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | DUSSAUZE, Marc | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | FARGIN, Evelyne | |
hal.structure.identifier | Institut de Chimie de la Matière Condensée de Bordeaux [ICMCB] | |
dc.contributor.author | CARDINAL, Thierry | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | TALAGA, David | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | ADAMIETZ, Frédéric | |
hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
dc.contributor.author | RODRIGUEZ, Vincent | |
dc.date.issued | 2014 | |
dc.identifier.issn | 1932-7447 | |
dc.description.abstractEn | Molecular and ionic species of nitrogen oxides have been injected, formed, and then trapped within a borosilicate glass during a thermal poling process. This original observation denotes a new aspect of poling mechanisms for ionic glasses. For each poled borosilicate glasses studied, compositional, structural, and second harmonic generation profiles of their subanodic polarized layers have been characterized. A description of the space charge implementation process, involving interactions between charged and chemically active species formed both within plasma discharges at the glass/electrode interface and within the polarized glass matrix, is proposed. | |
dc.language.iso | en | |
dc.publisher | American Chemical Society | |
dc.subject.en | Glasses | |
dc.subject.en | Thermal poling process | |
dc.subject.en | Nitrogen oxides | |
dc.subject.en | Borosilicate | |
dc.title.en | Trapped molecular and ionic species in poled borosilicate glasses : toward a rationalized description of thermal poling in glasses | |
dc.type | Article de revue | |
dc.identifier.doi | 10.1021/jp4101015 | |
dc.subject.hal | Chimie/Matériaux | |
bordeaux.journal | Journal of Physical Chemistry C | |
bordeaux.page | 3716-3723 | |
bordeaux.volume | 118 | |
bordeaux.issue | 7 | |
bordeaux.peerReviewed | oui | |
hal.identifier | hal-00968916 | |
hal.version | 1 | |
hal.popular | non | |
hal.audience | Internationale | |
hal.origin.link | https://hal.archives-ouvertes.fr//hal-00968916v1 | |
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