HIDOURI, Mourad; LÓPEZ, María Luisa; PICO, Carlos; WATTIAUX, Alain; BEN AMARA, Mongi

doi:10.1016/j.molstruc.2012.04.002

Metadatos

Mostrar el registro completo del ítem

Licencia de uso del documento

HIDOURI, Mourad
Matériaux Inorganiques

LÓPEZ, María Luisa
Departamento de Química Inorgánica I

PICO, Carlos
Departamento de Química Inorgánica I

Idioma

Article de revue

Este ítem está publicado en

Journal of Molecular Structure. 2012, vol. 1030, p. 145-148

Elsevier

Resumen en inglés

Synthesis, crystal structure, Mössbauer spectroscopy and magnetic susceptibility of a new phosphate KSrFe2(PO4)3 are described. This compound crystallizes with the unit cell parameter a = 9.809(2) Å of the cubic space group P213 and four formula units per cell. Its structure belongs to the well known langbeinite type. It consists of a 3D framework resulting from a corner-sharing between FeO6 octahedra and PO4 tetrahedra. This framework delimits two distinct cavities, statistically occupied by the K+ and Sr2+ ions. The Mössbauer spectroscopy gave clear evidence of the exclusive presence of octahedral Fe3+ ions. The magnetic susceptibility measurements revealed that the compound follows the Curie-Weiss behavior with an experimental effective moment per unit formula μ = 8.16 μB, consistent with the ideal spin only value of 8.37 μB.< Leer menos

Palabras clave en inglés

Inorganic materials

Chemical synthesis

Crystal structure

Magnetic measurements

Mössbauer spectroscopy

Metadatos

Licencia de uso del documento

Synthesis and characterization of a new iron phosphate KSrFe2(PO4)3 with a langbeinite type structure

Idioma

Este ítem está publicado en

Resumen en inglés

Palabras clave en inglés

DOI

Orígen

Centros de investigación