Self‐Assembly Synthesis of a [2]Catenane Co II Single‐Molecule Magnet
| dc.rights.license | open | en_US |
| dc.contributor.author | WILSON, Benjamin H. | |
| dc.contributor.author | WARD, Jas S. | |
| dc.contributor.author | YOUNG, David C. | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | LIU, Jun‐Liang | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | MATHONIÈRE, Corine | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | CLERAC, Rodolphe
IDREF: 103790411 | |
| dc.contributor.author | KRUGER, Paul E. | |
| dc.date.accessioned | 2022-06-28T08:10:36Z | |
| dc.date.available | 2022-06-28T08:10:36Z | |
| dc.date.issued | 2021-12 | |
| dc.identifier.issn | 1433-7851 | en_US |
| dc.identifier.other | https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202113837&file=anie202113837-sup-0001-1.cif | en_US |
| dc.identifier.other | https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202113837&file=anie202113837-sup-0001-2.cif | en_US |
| dc.identifier.other | https://onlinelibrary.wiley.com/action/downloadSupplement?doi=10.1002%2Fanie.202113837&file=anie202113837-sup-0001-misc_information.pdf | en_US |
| dc.identifier.uri | oai:crossref.org:10.1002/anie.202113837 | |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/140315 | |
| dc.description.abstractEn | We describe herein the self-assembly synthesis of an octanuclear CoII [2]catenane {[Co4(H2L)6]216+} formed by the mechanical interlocking of two {[Co4(H2L)6]8+} rectangles of unprecedented topology. Subtle manipulation of the synthetic conditions allows the isolation of a mixed-valence [Co2III/Co2II]10+ non-catenated rectangle. The CoII centers in the [2]catenane exhibit slow relaxation of their magnetic moment, i. e. single-molecule magnet properties, dominated by quantum tunneling and Raman relaxation processes. This work shows that metallo-supramolecular chemistry can precisely control the organization of single-molecule magnets in topologically complex arrangements. | |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by/3.0/us/ | * |
| dc.source | crossref | |
| dc.subject.en | Catenane | |
| dc.subject.en | Coordination Chemistry | |
| dc.subject.en | Mechanically Interlocked Molecules | |
| dc.subject.en | Single Molecule Magnetism | |
| dc.subject.en | Supramolecular Chemistry | |
| dc.title.en | Self‐Assembly Synthesis of a [2]Catenane Co II Single‐Molecule Magnet | |
| dc.title.alternative | Angew. Chem. Int. Ed. | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/anie.202113837 | en_US |
| dc.identifier.doi | 10.1002/anie.202113837 | |
| dc.identifier.doi | 10.1002/anie.202113837 | |
| dc.subject.hal | Chimie/Matériaux | en_US |
| bordeaux.journal | Angewandte Chemie International Edition | en_US |
| bordeaux.volume | 61 | en_US |
| bordeaux.hal.laboratories | Centre de Recherche Paul Pascal (CRPP) - UMR 5031 | en_US |
| bordeaux.issue | 4 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.team | Matériaux moléculaires et magnétisme (M3) | |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| bordeaux.import.source | dissemin | |
| hal.export | false | |
| workflow.import.source | dissemin | |
| dc.rights.cc | CC BY-ND | en_US |
| bordeaux.COinS | ctx_ver=Z39.88-2004&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.jtitle=Angewandte%20Chemie%20International%20Edition&rft.date=2021-12&rft.volume=61&rft.issue=4&rft.eissn=1433-7851&rft.issn=1433-7851&rft.au=WILSON,%20Benjamin%20H.&WARD,%20Jas%20S.&YOUNG,%20David%20C.&LIU,%20Jun%E2%80%90Liang&MATHONI%C3%88RE,%20Corine&rft.genre=article |
