MORENO, Kevin; MERLET, Eric; MCCLENAGHAN, Nathan; BUFFETEAU, Thierry; FERRAND, Yann; OLIVIER, Celine

doi:10.1002/cplu.202100051

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ChemPlusChem. 2021, vol. 86, n° 3, p. 496-503

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A series of functionalized quinoline-based aromatic oligoamide foldamers were prepared in their two enantiomeric forms, comprising an enantiopure terminal camphanyl chiral inducer, which governed the adjacent (P-/M-) helical-handedness. Hierarchical chirality transfer was further investigated in chromophore-appended variants via a range of electronic and vibrational spectroscopic techniques, including circularly polarized luminescence, vibrational circular dichroism and fluorescence. Intense total and polarized photoluminescence (up to phi(lum)=0.39, g(lum)=1.5x10(-3)) was observed in the visible region from these modular multicomponent architectures and a significant influence of positional isomerism was evidenced. The optimal position of a fluorophore substituent on the quinoline hexamers was determined as being position 2 over position 6, as stronger chiroptical features were systematically observed with the 2-positioned derivatives.< Réduire

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circularly polarized luminescence

foldamers

oligoamides

positional isomerism

vibrational circular dichroism

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Influence of Positional Isomerism on the Chiroptical Properties of Functional Aromatic Oligoamide Foldamers

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