Loading linear arrays of Cu(II) inside aromatic amide helices
| dc.rights.license | open | en_US |
| dc.relation.isnodouble | fa9ceb49-1614-4269-9360-66150af18b13 | * |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | WANG, Jinhua | |
| dc.contributor.author | WICHER, Barbara | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | MENDEZ-ARDOY, Alejandro | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | LI, Xuesong | |
| hal.structure.identifier | Centre de Recherche Paul Pascal [CRPP] | |
| dc.contributor.author | PECASTAINGS, Gilles | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | BUFFETEAU, Thierry | |
| hal.structure.identifier | Institut des Sciences Moléculaires [ISM] | |
| dc.contributor.author | BASSANI, Dario M. | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | MAURIZOT, Victor | |
| hal.structure.identifier | Chimie et Biologie des Membranes et des Nanoobjets [CBMN] | |
| dc.contributor.author | HUC, Ivan | |
| dc.date.accessioned | 2021-07-08T13:09:56Z | |
| dc.date.available | 2021-07-08T13:09:56Z | |
| dc.date.issued | 2021 | |
| dc.identifier.issn | 1433-7851 | en_US |
| dc.identifier.uri | https://oskar-bordeaux.fr/handle/20.500.12278/106468 | |
| dc.description.abstractEn | The very stable helices of 8-amino-2-quinolinecar-boxylic acid oligoamides are shown to uptake CuIIions in theircavity through deprotonation of their amide functions with minimal alteration of their shape, unlike most metallo-organicstructures which generally differ from their organic precursors.The outcome is the formation of intramolecular linear arrays of a defined number of CuIIcenters (up to sixteen in this study)at a 3 distance, forming a molecular mimic of a metal wirecompletely surrounded by an organic sheath. The helices packin the solid state so that the arrays of CuIIextend intermolecularly. Conductive-AFM and cyclic voltammetry suggest thatelectrons are transported throughout the metal-loaded helices in contrast with hole transport observed for analogous foldamers devoid of metal ions. | |
| dc.description.sponsorship | Les voies de signalisation du récepteur 5-HT6: de nouvelles cibles pour le traitement de la douleur neuropathique? - ANR-19-CE18-0018 | en_US |
| dc.language.iso | EN | en_US |
| dc.rights | Attribution-NonCommercial 3.0 United States | * |
| dc.rights.uri | http://creativecommons.org/licenses/by-nc/3.0/us/ | * |
| dc.subject.en | Cu(II)coordination | |
| dc.subject.en | electron transport | |
| dc.subject.en | helix | |
| dc.subject.en | metallofoldamers | |
| dc.subject.en | self-assembled monolayers | |
| dc.title.en | Loading linear arrays of Cu(II) inside aromatic amide helices | |
| dc.type | Article de revue | en_US |
| dc.identifier.doi | 10.1002/anie.202104734 | en_US |
| dc.subject.hal | Chimie/Matériaux | en_US |
| bordeaux.journal | Angewandte Chemie (International ed. in English) | en_US |
| bordeaux.page | 7p. | en_US |
| bordeaux.hal.laboratories | Institut de Chimie & de Biologie des Membranes & des Nano-objets (CBMN) - UMR 5248 | en_US |
| bordeaux.issue | 60 | en_US |
| bordeaux.institution | Université de Bordeaux | en_US |
| bordeaux.institution | Bordeaux INP | en_US |
| bordeaux.institution | CNRS | en_US |
| bordeaux.peerReviewed | oui | en_US |
| bordeaux.inpress | non | en_US |
| hal.identifier | hal-03281847 | |
| hal.version | 1 | |
| hal.date.transferred | 2021-07-08T13:10:00Z | |
| hal.export | true | |
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